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Join Claire Rourke live at White Hart Lane from 6pm GMT alongside Kop legends David Fairclough and Gary Gillespie for all the best build-up to the game.
Tottenham are managed by Tim Sherwood and Les Ferdinand and they finished top of their group in qualifying.
Rodolfo Borrell's side finished runners-up in their group to Sporting Lisbon who crashed out of the tournament at the quarter-final stage when they lost to Inter Milan.
Kick-off at White Hart Lane is at 7pm GMT.
Looking forward to the tie, skipper Conor Coady said: "It should be a good game, we play against English teams week in, week out so hopefully that will stand us in good stead.
"The competition has been a great learning curve for us. We've played against some top teams. All the teams have been different. Sporting Lisbon are fantastic and are a great footballing side. Wolfsburg and Molde were a bit more physical so it's been good to come up against different styles.
"I hope we still have a lot more to give. In the group stage we perhaps haven't showed what this Liverpool side can do, so hopefully we'll come out against Spurs and show everyone what we can do."
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6pm: Spurs v LFC LIVE on LFC TV
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Coady also explained the captaincy this season, with himself and Andre Wisdom sharing the armband for Rodolfo Borrell's side in 2011-12.
He added: "We had a meeting with Rodolfo at the start of the season. Andre was skipper of the reserves last season so Rodolfo wanted to keep some form of continuity. I'd been captain for his U18s so he asked me if I wanted to skipper the team in the NextGen, so I was delighted to accept it."